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Chloro(1,5-cyclooctadiene)iridium(I) Dimer

CAS Number: 12112-67-3

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Features

CAS Number:	12112-67-3
Linear Formula:	C₁₆H₂₄Cl₂Ir₂
Purity:	＞99%
Form:	Orange to dark red powder or crystals

Chloro(1,5-cyclooctadiene)iridium(I) Dimer Applications and Related Industries

● Precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins

● Precursor to catalyst for enantioselective reduction of imines

● Precursor to catalyst for allylic alkylation

● Precursor to catalyst for allylic amination and etherification

● Precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes

● Ir-catalyzed addition of acid chlorides to terminal alkynes

● Intramolecular hydroamination of unactivated alkenes with secondary alkyl- and arylamines

● Enantioselective [2+2] cycloaddition

● Silyl-directed, Ir-catalyzed ortho-borylation of arenes

● Ir-catalyzed cross-coupling of styrene derivatives with allylic carbonates

● Transfer hydrogenative C-C coupling

Chemical Identifiers

Linear Formula	C₁₆H₂₄Cl₂Ir₂
MDL Number	MFCD00012414
EC No.	235-170-7
Pubchem CID	6436381
IUPAC Name	(1Z,5Z)-cycloocta-1,5-diene; iridium; dichloride
SMILES	Cl[Ir].Cl[Ir].C=1CC\C=C/CCC=1.C/1C\C=C/CC\C=C\1
InchI Identifier	InChI=1S/2C8H12.2ClH.2Ir/c21-2-4-6-8-7-5-3-1;;;;/h21-2,7-8H,3-6H2;21H;;/q;;;;2+1/p-2/b2*2-1-,8-7-;;;;
InchI Key	ZFOUDQNHNLDNLD-MIXQCLKLSA-L

Chloro(1,5-cyclooctadiene)iridium(I) Dimer Properties (Theoretical)

Compound Formula	C₁₆H₂₄Cl₂Ir₂^-2
Molecular Weight	671.7
Appearance	Orange to dark red powder or crystals
Melting Point	190 °C
Boiling Point	N/A
Density	N/A
Solubility in H2O	N/A
Exact Mass	670.049021
Monoisotopic Mass	672.051354
Charge	-2

Chloro(1,5-cyclooctadiene)iridium(I) Dimer Health & Safety Information