PRODUCTS
Features
|
CAS Number: |
14871-41-1 |
|
Linear Formula: |
IrCl(CO)[P(C6H5)3]2 |
|
Purity: |
＞99% |
|
Form: |
Yellow crystalline solid |
✅ Product Description
Carbonylchlorobis(triphenylphosphine)iridium(I), commonly referred to as Iridium(I) chloride carbonyl bis(triphenylphosphine), is a high-purity coordination complex featuring iridium in the +1 oxidation state. With two triphenylphosphine ligands and one carbonyl ligand coordinated to an iridium center, this compound plays a significant role in homogeneous catalysis, organometallic synthesis, and advanced material research.
This yellow crystalline complex exhibits excellent solubility in non-polar organic solvents and serves as a valuable precursor for a wide range of iridium-based catalysts. Owing to its electron-rich and structurally stable characteristics, it is widely employed in hydrogenation, hydroformylation, and other catalytic processes under mild conditions.
🔹 Features & Properties
📌 Molecular Formula: IrCl(CO)[P(C₆H₅)₃]₂
📌 Molecular Weight: ~771.12 g/mol
📌 Appearance: Yellow crystalline solid
📌 Purity: >99%
📌 Solubility: Soluble in organic solvents such as chloroform, toluene, and dichloromethane
📌 Stability: Air-stable in solid form; moisture-sensitive in solution
📌 Structure: Square planar coordination geometry
🚀 Applications & Related Industries
✅ Homogeneous Catalysis: Key precursor in hydrogenation, carbonylation, and hydroformylation reactions
✅ Fine Chemical Synthesis: Used in selective bond activation and ligand exchange reactions
✅ Organometallic Chemistry: Widely used in academic and industrial research
✅ OLED and Photonic Materials: Starting material for iridium-based emitters
✅ Pharmaceutical R&D: Involved in synthesis of intermediates under mild catalytic conditions
📖 Synonyms
Iridium(I) carbonyl chloride bis(triphenylphosphine)
IrCl(CO)(PPh₃)₂
Iridium chloride carbonyl bis(triphenylphosphine)
⚠ Health & Safety Information
⚠ Hazard Statements: Harmful if swallowed or inhaled
⚠ Use protective gloves, safety goggles, and handle in a fume hood
Store in a dry, well-ventilated area, away from light and moisture
Dispose of according to local environmental regulations and safety codes
🏭 Production Method & Equipment
This complex is synthesized via ligand substitution reaction between iridium chloride and triphenylphosphine in a carbonylating environment under inert gas. The reaction is carried out in anhydrous organic solvents and followed by purification through crystallization or column chromatography.
📐 Size & Customization
Available in: 100 mg, 1 g, 5 g, 10 g, and bulk quantities
Custom purity grades and special packaging available upon request
📋 Certifications & Quality Assurance
Conforms to ASTM, GB, EN, and BS standards
COA, MSDS, and NMR/Spectroscopic data available
High-purity batches produced under ISO 9001 certified quality management
Third-party analytical testing available upon request
⏱ Lead Time & MOQ
Lead Time: 7–10 working days depending on order quantity
MOQ: 100 mg (lab use); 1 g (industrial/R&D use)
💬 FAQs (Frequently Asked Questions)
Q1: What solvents is this compound soluble in?
A1: It is soluble in organic solvents like dichloromethane, chloroform, and toluene.
Q2: What is the primary use of this iridium complex?
A2: It is used extensively in homogeneous catalysis, especially in hydrogenation and hydroformylation reactions.
Q3: Is it air or moisture sensitive?
A3: It is stable in solid form under ambient conditions but should be handled under inert atmosphere when in solution.
🧭 How to Choose the Product
Choose standard >99% purity for most catalytic and synthetic applications
Specify preferred form (powder, crystalline, or pre-dissolved solutions) if applicable
Consider packaging options depending on scale: lab packs or industrial drums
📏 Product Standards
Conforms to ASTM, GB, EN, and BS standards
Additional compliance available upon request (e.g., RoHS, REACH)
🧪 Production & Quality Control
Synthesized under inert conditions in controlled environments
Final product is analyzed by NMR, IR, MS, and elemental analysis
Packaged in moisture-proof vials with tamper-evident seals
Traceable batch ID for every shipment
📦 Shipping & Delivery Information
Vacuum-sealed or argon-filled glass vials for moisture-sensitive materials
Available in laboratory-scale or bulk packaging options
Delivered with full documentation: COA, MSDS, analytical data sheets
🌱 Environmental Impact & Sustainability
Precious metal recycling programs available for used iridium catalysts
Manufactured with minimal waste and solvent recycling procedures
Compliant with environmental regulations for hazardous materials
🧼 Maintenance & Care Instructions
Keep container tightly sealed under inert atmosphere
Avoid exposure to moisture, light, and air in open solutions
Best stored at room temperature in a dry cabinet
🧩 Differentiation Between Products
Compared to other iridium phosphine complexes, Carbonylchlorobis(triphenylphosphine)iridium(I) offers superior catalytic activity and solution stability. The presence of a CO ligand enhances its electron-donating ability, making it particularly useful in mild condition transformations.
📩 Contact Us
Reach out to our team for pricing, technical data, COA, or customized solutions tailored to your application needs.
Chemical Identifiers
|
Linear Formula |
IrCl(CO)[P(C6H5)3]2 |
|
MDL Number |
MFCD00009590 |
|
EC No. |
238-941-6 |
|
Pubchem CID |
84678 |
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IUPAC Name |
carbon monoxide; iridium; triphenylphosphane; chloride |
|
SMILES |
[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Ir] |
|
InchI Identifier |
InChI=1S/ 2C18H15P.CO.ClH.Ir/ c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/ h2*1-15H;;1H;/p-1 |
|
InchI Key |
VSPLSJCNZPDHCN-UHFFFAOYSA-M |
Carbonylchlorobis(triphenylphosphine)iridium(I) Properties (Theoretical)
|
Compound Formula |
C37H30ClIrOP2 |
|
Molecular Weight |
780.251 |
|
Appearance |
Yellow crystalline solid |
|
Melting Point |
215°C |
|
Boiling Point |
360 °C |
|
Density |
N/A |
|
Solubility in H2O |
Insoluble |
|
Exact Mass |
780.108968 |
|
Monoisotopic Mass |
780.108968 |
|
Charge |
-1 |
Carbonylchlorobis(triphenylphosphine)iridium(I) Health & Safety Information
|
Signal Word |
Danger |
|
Hazard Statements |
H301+H311+H331-H315-H319 |
|
Hazard Codes |
T |
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Precautionary Statements |
P261-P280h-P304+P340-P311a-P405-P501a |
|
Risk Codes |
20/21/22 |
|
Safety Statements |
4-9-20-36/37/39-45-60 |
|
RTECS Number |
N/A |
|
Harmonized Tariff Code |
2843.90 |
|
Transport Information |
UN2811 6.1/PG III |
|
WGK Germany |
N/A |
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GHS Pictograms |
GHS06 Skull and Crossbones
GHS07 Exclamation Point
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