PRODUCTS
Features
|
CAS Number: |
14871-41-1 |
|
Linear Formula: |
IrCl(CO)[P(C6H5)3]2 |
|
Purity: |
๏ผ99% |
|
Form: |
Yellow crystalline solid |
โ
Product Description
Carbonylchlorobis(triphenylphosphine)iridium(I), commonly referred to as Iridium(I) chloride carbonyl bis(triphenylphosphine), is a high-purity coordination complex featuring iridium in the +1 oxidation state. With two triphenylphosphine ligands and one carbonyl ligand coordinated to an iridium center, this compound plays a significant role in homogeneous catalysis, organometallic synthesis, and advanced material research.
This yellow crystalline complex exhibits excellent solubility in non-polar organic solvents and serves as a valuable precursor for a wide range of iridium-based catalysts. Owing to its electron-rich and structurally stable characteristics, it is widely employed in hydrogenation, hydroformylation, and other catalytic processes under mild conditions.
๐น Features & Properties
๐ Molecular Formula: IrCl(CO)[P(CโHโ )โ]โ
๐ Molecular Weight: ~771.12 g/mol
๐ Appearance: Yellow crystalline solid
๐ Purity: >99%
๐ Solubility: Soluble in organic solvents such as chloroform, toluene, and dichloromethane
๐ Stability: Air-stable in solid form; moisture-sensitive in solution
๐ Structure: Square planar coordination geometry
๐ Applications & Related Industries
โ Homogeneous Catalysis: Key precursor in hydrogenation, carbonylation, and hydroformylation reactions
โ Fine Chemical Synthesis: Used in selective bond activation and ligand exchange reactions
โ Organometallic Chemistry: Widely used in academic and industrial research
โ OLED and Photonic Materials: Starting material for iridium-based emitters
โ Pharmaceutical R&D: Involved in synthesis of intermediates under mild catalytic conditions
๐ Synonyms
Iridium(I) carbonyl chloride bis(triphenylphosphine)
IrCl(CO)(PPhโ)โ
Iridium chloride carbonyl bis(triphenylphosphine)
โ Health & Safety Information
โ Hazard Statements: Harmful if swallowed or inhaled
โ Use protective gloves, safety goggles, and handle in a fume hood
Store in a dry, well-ventilated area, away from light and moisture
Dispose of according to local environmental regulations and safety codes
๐ญ Production Method & Equipment
This complex is synthesized via ligand substitution reaction between iridium chloride and triphenylphosphine in a carbonylating environment under inert gas. The reaction is carried out in anhydrous organic solvents and followed by purification through crystallization or column chromatography.
๐ Size & Customization
Available in: 100 mg, 1 g, 5 g, 10 g, and bulk quantities
Custom purity grades and special packaging available upon request
๐ Certifications & Quality Assurance
Conforms to ASTM, GB, EN, and BS standards
COA, MSDS, and NMR/Spectroscopic data available
High-purity batches produced under ISO 9001 certified quality management
Third-party analytical testing available upon request
โฑ Lead Time & MOQ
Lead Time: 7–10 working days depending on order quantity
MOQ: 100 mg (lab use); 1 g (industrial/R&D use)
๐ฌ FAQs (Frequently Asked Questions)
Q1: What solvents is this compound soluble in?
A1: It is soluble in organic solvents like dichloromethane, chloroform, and toluene.
Q2: What is the primary use of this iridium complex?
A2: It is used extensively in homogeneous catalysis, especially in hydrogenation and hydroformylation reactions.
Q3: Is it air or moisture sensitive?
A3: It is stable in solid form under ambient conditions but should be handled under inert atmosphere when in solution.
๐งญ How to Choose the Product
Choose standard >99% purity for most catalytic and synthetic applications
Specify preferred form (powder, crystalline, or pre-dissolved solutions) if applicable
Consider packaging options depending on scale: lab packs or industrial drums
๐ Product Standards
Conforms to ASTM, GB, EN, and BS standards
Additional compliance available upon request (e.g., RoHS, REACH)
๐งช Production & Quality Control
Synthesized under inert conditions in controlled environments
Final product is analyzed by NMR, IR, MS, and elemental analysis
Packaged in moisture-proof vials with tamper-evident seals
Traceable batch ID for every shipment
๐ฆ Shipping & Delivery Information
Vacuum-sealed or argon-filled glass vials for moisture-sensitive materials
Available in laboratory-scale or bulk packaging options
Delivered with full documentation: COA, MSDS, analytical data sheets
๐ฑ Environmental Impact & Sustainability
Precious metal recycling programs available for used iridium catalysts
Manufactured with minimal waste and solvent recycling procedures
Compliant with environmental regulations for hazardous materials
๐งผ Maintenance & Care Instructions
Keep container tightly sealed under inert atmosphere
Avoid exposure to moisture, light, and air in open solutions
Best stored at room temperature in a dry cabinet
๐งฉ Differentiation Between Products
Compared to other iridium phosphine complexes, Carbonylchlorobis(triphenylphosphine)iridium(I) offers superior catalytic activity and solution stability. The presence of a CO ligand enhances its electron-donating ability, making it particularly useful in mild condition transformations.
๐ฉ Contact Us
Reach out to our team for pricing, technical data, COA, or customized solutions tailored to your application needs.
Chemical Identifiers
|
Linear Formula |
IrCl(CO)[P(C6H5)3]2 |
|
MDL Number |
MFCD00009590 |
|
EC No. |
238-941-6 |
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Pubchem CID |
84678 |
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IUPAC Name |
carbon monoxide; iridium; triphenylphosphane; chloride |
|
SMILES |
[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Ir] |
|
InchI Identifier |
InChI=1S/ 2C18H15P.CO.ClH.Ir/ c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/ h2*1-15H;;1H;/p-1 |
|
InchI Key |
VSPLSJCNZPDHCN-UHFFFAOYSA-M |
Carbonylchlorobis(triphenylphosphine)iridium(I) Properties (Theoretical)
|
Compound Formula |
C37H30ClIrOP2 |
|
Molecular Weight |
780.251 |
|
Appearance |
Yellow crystalline solid |
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Melting Point |
215°C |
|
Boiling Point |
360 °C |
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Density |
N/A |
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Solubility in H2O |
Insoluble |
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Exact Mass |
780.108968 |
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Monoisotopic Mass |
780.108968 |
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Charge |
-1 |
Carbonylchlorobis(triphenylphosphine)iridium(I) Health & Safety Information
|
Signal Word |
Danger |
|
Hazard Statements |
H301+H311+H331-H315-H319 |
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Hazard Codes |
T |
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Precautionary Statements |
P261-P280h-P304+P340-P311a-P405-P501a |
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Risk Codes |
20/21/22 |
|
Safety Statements |
4-9-20-36/37/39-45-60 |
|
RTECS Number |
N/A |
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Harmonized Tariff Code |
2843.90 |
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Transport Information |
UN2811 6.1/PG III |
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WGK Germany |
N/A |
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GHS Pictograms |
GHS06 Skull and Crossbones
GHS07 Exclamation Point
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