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Beryllia Ceramics

Beryllia Ceramics

CAS No.: 1304-56-9

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Features

CAS No.:

1304-56-9

Linear Formula:

BeO

Material:

Beryllium Oxide

Purity:

97%, 99%

Appearance:

White Solid

Shape:

Rod, Tube, Plate, Sheet, Disc, and Customized Parts

Size:

Customized

Processing Methods:

Cold Isostatic Press, Dry Press, Tape Casting, Precision Machining Processing, etc.

Beryllia Ceramics Description

Beryllium oxide (BeO), which is commonly referred to as beryllia, is endowed with a virtuously unique combination of thermal, electrical, optical, and mechanical properties which may be exploited for a diverse range of applications.

BeO provides all the desirable physical and dielectric characteristics exhibited by aluminum oxide or aluminum nitride and, in addition, offers thermal conductivity ten times higher than alumina, and fifty percent higher than aluminum nitride, a dielectric constant that is lower than both alumina and aluminum nitride, and weight per given volume that is fully a quarter less than alumina, and nearly ten percent less than aluminum nitride. As a thermally conductive and electrically insulating material, its performance is exceeded only by that of diamond.

Although high-purity beryllium oxide ceramics are very safe, it cannot be ignored that beryllium oxide dust is toxic to the human body. This is like plastics that do not produce toxins when they are used, but the materials made of plastics are generally toxic for the same reason. Beryllium oxide ceramics processed into solid forms will not cause special harm to human health.

Characteristics of Beryllia Ceramics

● Apart from reactivity with water vapor at high temperature (1000°C), BeO is one of the most chemically stable oxides, resisting both carbon reduction and molten metal attack at high temperatures.

● The thermal conductivity of BeO is extremely high in comparison with other ceramics, particularly below 300°C. For comparison, the thermal conductivity of Beryllium Oxide at Room Temperature is 285 W/mK, for copper it is 400 W/mK, for aluminum nitride it is 180 W/mK, and for diamond it is 2000 W/mK.

● BeO is classified as an electrical insulator with a bulk Resistivity on the order of 1016Ωcm.

● The mechanical strength is normally lower than that of alumina. Its fracture toughness is generally about half that of alumina; but with good design and controlled fabrication processing acceptable strength can be achieved for commercial applications of BeO.

● BeO has relatively very good thermal shock resistance due to its high thermal conductivity.

● Beryllium oxide has a density fully 25% lower than Alumina. Comparing theoretical density values, BeO is 3.01g/cc while Al2O3 is 4.00 g/cc and AlN is 3.26 g/cc.

● The coefficient of thermal Expansion for BeO is comparable to many other oxide ceramics and many metals, as well, at approximately 7.5 in./in./°C for the range from 25°C - 1000°C.

Mechanical Properties of Beryllia Ceramics

Properties

Unit

97%BeO

99%BeO

99%Al2O3

Colour

——

White

White

Yellow

Density

g/cm³

≥2.85

≥2.85

3.85

Flexural Strength

MPa

≥170

≥190

310

Air Tightness

Pa.m³/s

≤10×10-11

≤10×10-11

——

Average Grain Size

um

12~30

12~30

——

Thermal Properties of Beryllia Ceramics

Properties

Unit

97%BeO

99%BeO

99%Al2O3

Maximum Use Temperature

℃(No load)

1600

1600

1650

Thermal Conductivity @ 25°C

W/(m・K)

≥200

≥240

29

Thermal Conductivity @ 100°C

W/(m・K)

≥160

≥190

——

Thermal Expansion a at 25–500°C

1 x 10-6/°C

7~8.5

7~8.5

7~8

Thermal Shock Resistance

℃(Put in water)

800

800

200

Electrical Properties of Beryllia Ceramics

Properties

Unit

97%BeO

99%BeO

99%Al2O3

Dielectric Constant

1MHz

6.9±0.4

6.9±0.4

9.9

Dielectric Strength

KV/mm

50

50

15

Dielectric Loss

1MHz

4 x 10-4

4 x 10-4

4 x 10-4

Volume Resistivity @ 25°C

Ω・cm

>1014

>1014

>1014

Volume Resistivity @ 300°C

Ω・cm

>1011

>1011

>108

Beryllia Ceramics Applications and Related Industries

● Medical: gas lasers for DNA and tissue analysis, confocal and wide field fluorescence microscopy equipment, portable defibrillators, telecom infrastructure, transistors and terminations in the wireless system

● Lasers: high end laser diodes for commercial systems, industrial laser metal cutting and marking equipment, long range fiber optic transmission

● Semiconductor Handling Equipment: end-effectors and arm components, wafer chucks, crucibles for high temperature melting

● Energy: oil and gas exploration, in situ x-ray analysis for down-hole drilling, concentrating photovoltaic (CPV) systems optoelectronics, transmitters, receivers, modulators, and switches, power amplifiers and drivers

● Military and Aerospace: radar modules, guidance modules, microwave and millimeter-wave communications modules

● Wireless Communications: point-to-point and point-to-multipoint radios, satellite communication modules

Chemical Identifiers

Linear Formula

BeO

MDL Number

MFCD00003457

EC No.

215-133-1

Beilstein/Reaxys No.

N/A

Pubchem CID

14775

IUPAC Name

Oxoberyllium

SMILES

[Be]=O

InchI Identifier

InChI=1S/Be.O

InchI Key

LTPBRCUWZOMYOC-UHFFFAOYSA-N

Beryllium Oxide Properties (Theoretical)

Compound Formula

BeO

Molecular Weight

25.01

Appearance

White powder

Melting Point

2507 °C (4545 °F)

Boiling Point

3900 °C (7052 °F)

Density

2.9 g/cm3

Solubility in H2O

N/A

Electrical Resistivity

13 10x Ω-m

Poisson's Ratio

0.26

Specific Heat

1050 J/kg-K

Tensile Strength

140 MPa (Ultimate)

Thermal Conductivity

270 W/m-K

Thermal Expansion

8.0 µm/m-K

Young's Modulus

350 GPa

Exact Mass

25.0071

Monoisotopic Mass

25.007097 Da

Beryllium Oxide Health & Safety Information

Signal Word

Danger

Hazard Statements

H301-H315-H317-H319-H330-H335-H350i-H372

Hazard Codes

T+

Precautionary Statements

P201-P260-P280-P284-P301 + P310-P305 + P351 + P338

Flash Point

Not applicable

Risk Codes

49-25-26-36/37/38-43-48/23

Safety Statements

53-45

RTECS Number

DS4025000

Transport Information

UN 1566 6.1 / PGII

WGK Germany

3

GHS Pictograms

GHS06 Skull and Crossbones

image011

GHS08 Health Hazard

image010


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